Visible absorption bands of the (O2)2 collision complex at pressures below 760 Torr.

The collision-induced absorption of oxygen in the 540-650-nm wavelength region has been measured ata pressure range from 0 to 730 Torr at T 5 294 K. Pressure-dependent cross sections of the X 3Sigmag(+)+X 3Sigmag alpha 1Deltag(nu =0) + alpha 1Deltag(nu = 1 ) and X 3Simag(+)+ X 3Sigmag+--> alpha 1Deltag(nu =0) + 1 alpha 1Deltag (nu = 0) transitions have been determined by means of cavity-ringdown spectroscopy. Contributions of the overlapping g and d bands of O2 have been evaded, and Rayleigh extinction has been taken into account.